Chemıcal reactıon Engıneerıng: Beyond the fundamentals

L.K. Doraiswamy, Deniz Uner

table of contents

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Part III Beyond the Fundamentals

  • Objectives
  • Introduction
  • The different tools of the trade
  • Process intensification
  • References

Fixed-bed reactor design for solid catalyzed fluid-phase reactions

  • Chapter objectives
  • Introduction
  • Nonisothermal, nonadiabatic, and adiabatic reactors
  • Adiabatic reactor
  • Choice between NINA-PBR and A-PBR
  • Alternative fixed-bed designs
  • References
  • Bibliography
  • Explore Yourself

Fluidized-bed reactor design for solid catalyzed fluid-phase reactions

  • Chapter objectives
  • General comments
  • Fluidization: Some basics
  • Two-phase theory of fluidization
  • Geldart’s classification
  • Bubbling bed model of fluidized-bed reactors
  • Solids distribution
  • Calculation of conversion
  • Strategies to improve fluid-bed reactor performance
  • Extension to other regimes of fluidization types of reactors
  • Deactivation control
  • Some practical considerations
  • Fluidized-bed versus fixed-bed reactors
  • References
  • Explore Yourself

Gas–solid noncatalytic reactions and reactors

  • Chapter objectives
  • Introduction
  • Modeling of gas–solid reactions
  • Extensions to the basic models
  • Models that account for structural variations
  • A general model that can be reduced to specific ones
  • Gas–solid noncatalytic reactors
  • References

Gas–liquid and liquid–liquid reactions and reactors

  • Chapter objectives
  • Introduction
  • Diffusion accompanied by an irreversible reaction of general order
  • Measurement of mass transfer coefficients
  • Reactor design
  • A generalized form of equation for all regimes
  • Classification of gas–liquid contactors
  • Reactor design for gas–liquid reactions
  • Reactor choice
  • Liquid–liquid contactors
  • Stirred tank reactor: Some practical considerations
  • References
Multiphase reactions and reactors
  • Chapter objectives
  • Introduction
  • Design of three-phase catalytic reactors
  • Types of three-phase reactors
  • Loop slurry reactors
  • Collection and interpretation of laboratory data for three-phase catalytic reactions
  • Three-phase noncatalytic reactions
  • References
  • Bibliography
  • Membrane-assisted reactor engineering
  • Introduction
  • General considerations
  • Modeling of membrane reactors
  • Operational features
  • Comparison of reactors
  • Examples of the use of membrane reactors in organic technology/synthesis
  • References

Membrane-assisted reactor engineering

  • Introduction
  • General considerations
  • Modeling of membrane reactors
  • Operational featuresComparison of reactors
  • Examples of the use of membrane reactors in organic technology/synthesis
  • References

Combo reactors: Distillation column reactors

  • Distillation column reactor
  • Enhancing role of distillation: Basic principle
  • Overall effectiveness factor in a packed DCR
  • Distillation–reaction
  • References

Homogeneous catalysis

  • Introduction
  • Formalisms in transition metal catalysis
  • Operational scheme of homogeneous catalysis
  • Basic reactions of homogeneous catalysis
  • Main features of transition metal catalysis in organic synthesis: A summary
  • A typical class of industrial reactions: Hydrogenation
  • General kinetic analysis
  • References

Phase-transfer catalysis

  • Introduction
  • Fundamentals of PTC
  • Mechanism of PTC
  • Modeling of PTC reactions
  • "Cascade engineered" PTC process
  • References

Forefront of the chemical reaction engineering field

  • Objective
  • Introduction
  • Resource economy
  • Energy economy
  • Chemical reaction engineer in the twenty-first century
  • In Closing

Index